{"id":66,"date":"2016-10-28T14:09:34","date_gmt":"2016-10-28T05:09:34","guid":{"rendered":"https:\/\/www.org-synth.chem.sci.titech.ac.jp\/ohmorilab\/wordpress\/?page_id=66"},"modified":"2022-01-30T12:02:45","modified_gmt":"2022-01-30T03:02:45","slug":"%e7%99%ba%e8%a1%a8%e8%ab%96%e6%96%87-2","status":"publish","type":"page","link":"https:\/\/www.org-synth.chem.sci.titech.ac.jp\/?page_id=66","title":{"rendered":"\u767a\u8868\u8ad6\u6587"},"content":{"rendered":"<ul id=\"cnav\">\n<li><a href=\"https:\/\/www.org-synth.chem.sci.titech.ac.jp\/?page_id=16\/\">2021\u5e74\u4ee5\u964d<\/a><\/li>\n<li><a href=\"https:\/\/www.org-synth.chem.sci.titech.ac.jp\/?page_id=16\/#2016-2020\">2016-2020\u5e74<\/a><\/li>\n<li><a href=\"https:\/\/www.org-synth.chem.sci.titech.ac.jp\/?page_id=16\/#2011-2015\">2011-2015\u5e74<\/a><\/li>\n<li><a href=\"https:\/\/www.org-synth.chem.sci.titech.ac.jp\/?page_id=16\/#2006-2010\">2006-2010\u5e74<\/a><\/li>\n<li><a href=\"https:\/\/www.org-synth.chem.sci.titech.ac.jp\/?page_id=16\/#2001-2005\">2001-2005\u5e74<\/a><\/li>\n<li><a href=\"https:\/\/www.org-synth.chem.sci.titech.ac.jp\/?page_id=66\/#1996-2000\">1996-2000\u5e74<\/a><\/li>\n<li><a href=\"https:\/\/www.org-synth.chem.sci.titech.ac.jp\/?page_id=66\/#1991-1995\">1991-1995\u5e74<\/a><\/li>\n<li><a href=\"https:\/\/www.org-synth.chem.sci.titech.ac.jp\/?page_id=66\/#1986-1990\">1986-1990\u5e74<\/a><\/li>\n<li><a href=\"https:\/\/www.org-synth.chem.sci.titech.ac.jp\/?page_id=66\/#1978-1985\">1978-1985\u5e74<\/a><\/li>\n<li><a href=\"https:\/\/www.org-synth.chem.sci.titech.ac.jp\/?page_id=52\">\u8457 \u66f8<\/a><\/li>\n<\/ul>\n<h2 id=\"1996-2000\">1996-2000\u5e74<\/h2>\n<table class=\"color\">\n<tbody>\n<tr>\n<td>127.<\/td>\n<td>Synthestic Study of Aquayamycin. Part 3: First Total Synthesis, <em>Tetrahedron Lett<\/em>., <strong>41<\/strong>, 8393\uff0d8396 (2000), by T. Matsumoto, H. Yamaguchi, M. Tanabe, Y. Yasui, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>126.<\/td>\n<td>Synthestic Study of Aquayamycin. Part 2: Synthesis of the AB Ring Fragment, <em>Tetrahedron Lett<\/em>., <strong>41<\/strong>, 8389\uff0d8392 (2000), by H. Yamaguchi, T. Konegawa, M. Tanabe, T. Nakamura, T. Matsumoto, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>125.<\/td>\n<td>Synthestic Study of Aquayamycin. Part 1: Synthesis of 3-(Phenylsulfonyl)phthalides Possessing a b-<em>C<\/em>-Olivoside, <em>Tetrahedron Lett<\/em>.,<strong> 41<\/strong>, 8383\uff0d8387 (2000), by T. Matsumoto, H. Yamaguchi, T. Hamura, M. Tanabe, Y. Kuriyama, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>124.<\/td>\n<td>Synthetic Study of Hybrid Natural Products, Ravidomycin, <em>Pure Appl. Chem.,<\/em> 1783\uff0d1786 (2000), by K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>123.<\/td>\n<td>Glycosylation Study on Pradimicin\uff0dBenanomicin Antibiotics, <em>Tetrahedron Lett<\/em>., <strong>41<\/strong>, 6827\uff0d6832 (2000), by H. Kato, K. Ohmori, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>122.<\/td>\n<td>First Total Synthesis of Astilbin, A Biologically Active Glycosyl Flavonoid isolated from Chinese Folk Medicine, <em>Tetrahedron Lett<\/em>., <strong>41<\/strong>, 5537\uff0d5541 (2000), by K. Ohmori, H. Ohrui, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>121.<\/td>\n<td>Thermodynamic and Kinetic Properties of <em>trans<\/em>-3, 4, 5, 6-Tetramethyl-9, 10-dihydroxy-9,10-dihydrophenanthrene: Pseudo-Rotational Barriers around Biphenyl Axis, <em>Chirality, <\/em><strong>12<\/strong>, 548\uff0d550 (2000), by H. Kato, K. Ohmori, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>120.<\/td>\n<td>Silicon-Directed Regioselective [2+2] Cycloaddition of a-Alkoxybenzyne and Ketene Silyl Acetals, <em>Synlett, <\/em><strong>2000<\/strong>, 520\uff0d522, by T. Hosoya, T. Hamura, Y. Kuriyama, M. Miyamoto, T. Matsumoto, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>119.<\/td>\n<td>Total Synthesis of Ravidomycin: Revision of Absolute and Relative Stereochemistry, <em>Tetrahedron Lett<\/em>., <strong>41<\/strong>, 1063\uff0d1067 (2000), by S. Futagami, Y. Ohashi, K. Imura, T. Hosoya, K. Ohmori, T. Matsumoto, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>118.<\/td>\n<td>Hf-Centered Lewis Acids in Organic Synthesis, H. Yamamoto ed., Handbook on Lewis Acids \uff0d Application in Organic Synthesis, Wiley\uff0dVCH, Chapt.17, by K. Suzuki and S. Yamanoi.<\/td>\n<\/tr>\n<tr>\n<td>117.<\/td>\n<td>Alkylzirconation of 1-Alkynes Catalyzed by Triphenylcarbenium Tetrakis(pentafluoro)borate, <em>Tetrahedron Lett.<\/em>,<strong> 40<\/strong>, 8407\uff0d8410 (1999)<em>,<\/em> by S. Yamanoi, H. Ohrui, K. Seki, T. Matsumoto, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>116.<\/td>\n<td>Divergent Behavior of Cobalt-Complexed Enynyl Compounds Having a Leaving Group, <em>Tetrahedron Lett.<\/em>,<strong> 40<\/strong>, 4563\uff0d4566 (1999), by M. Kitamura, K. Ohmori, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>115.<\/td>\n<td>Total Synthesis of Pradimicinone, the Common Aglycon of the Pradimicin\uff0dBenanomicin Antibiotics, <em>Angew. Chem., Int. Ed., Engl.,<\/em><strong> 38<\/strong>, 1229\uff0d\uff0d1232 (1999), by M. Kitamura, K. Ohmori, T. Kawase, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>114.<\/td>\n<td>From Axial Chirality to Central Chiralities: Pinacol Cyclization of 2,2\u2019-Biaryldicarbaldehyde en route to <em>trans<\/em>-9,10-Dihydrophenathren-9,10-diol Substructure of Pradimicin\uff0dBenanomicin Antibiotics, <em>Angew. Chem., Int. Ed., Engl., <\/em><strong>38<\/strong>, 1226\uff0d1229 (1999), by K. Ohmori, M. Kitamura, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>113.<\/td>\n<td>Reaction of 1-Iodoalkynes with Allylzirconiums : Generation of Alkylidene Carbenoid via Allylmetallation, <em>Tetrahedron Lett.<\/em>, <strong>40<\/strong>, 2793\uff0d2796 (1999), by S. Yamanoi, T. Matsumoto, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>112.<\/td>\n<td>Zr- and Hf-Centered Lewis Acid in Organic Synthesis, in H. Yamamoto Ed., Lewis Acid Reagents: A Practical Approach, Chapt. 10, pp. 177\uff0d184, Oxford Univ. Press (1999), by K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>111.<\/td>\n<td>Regioselectivity of MAO-Catalyzed Allylmetallation of Conjugated Enynes with Allylzirconiums,<em> Tetrahedron Lett.<\/em>,<strong> 39<\/strong>, 9727\uff0d9730 (1998), by S. Yamanoi, T. Matsumoto, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>110.<\/td>\n<td>Total Synthesis of the Furaquinocins, <em>J. Am. Chem. Soc., <\/em><strong>120<\/strong>, 11633\uff0d11644 (1998), by T. Saito, T. Suzuki, C. Akiyama, T. Ochiai, K. Takeuchi, T. Matsumoto, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>109.<\/td>\n<td>Base-Induced Rearrangement of 2-Vinylbenzocyclobutenol into Substituted Naphthalene Derivatives, <em>Tetrahedron Lett.<\/em>, <strong>39<\/strong>, 4853\uff0d4856 (1998), by T. Matsumoto, T. Hamura, M. Miyamoto, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>108.<\/td>\n<td>Isochroman-3-ones via Site Selective Ring Opening of Benzocyclobutenone Promoted by Lithium Tetramethylpiperidide and Reaction with Aromatic Aldehydes, <em>Tetrahedron Lett<\/em>., <strong>38<\/strong>, 8985\uff0d8988 (1997), T. Matsumoto, T. Hamura, Y. Kuriyama, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>107.<\/td>\n<td>Unusual Regioselectivity in the Reductive Coupling of Alkynes and Allenes via Hydrozirconation and Zinca-Claisen Rearrangement: <em>Angew. Chem., Int. Ed. Engl.,<\/em> <strong>36<\/strong>, 2469\uff0d2471 (1997), <em>Angew. Chem.,<\/em> <strong>109<\/strong>, 2578\uff0d2580 (1997), by K. Suzuki, T. Imai, S. Yamanoi, M. Chino, and T. Matsumoto.<\/td>\n<\/tr>\n<tr>\n<td>106.<\/td>\n<td>Implication and Improvement of Stereoselective Methylenation of Chiral Aldehyde in Total Synthesis of the Furaquinocins, <em>Tetrahedron Lett<\/em>., <strong>38<\/strong>, 3755\uff0d3758 (1997), by T. Saito, T. Suzuki, K. Takeuchi, T. Matsumoto, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>105.<\/td>\n<td><em>C<\/em>-Glycosyl Juglone in Angucycline Synthesis: Total Synthesis of Galtamycinon, the Common Aglycon of the <em>C<\/em>-Glycosyl Naphthacenequinone-Type Angucyclines, <em>Tetrahedron<\/em>, <strong>53<\/strong>, 16533\uff0d16544 (1997), by T. Matsumoto, H. Yamaguchi, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>104.<\/td>\n<td>MAO-Catalyzed Allylmetallation of Alkynes, <em>Tetrahedron Lett<\/em>., <strong>38<\/strong>, 3031\uff0d3034 (1997), by S. Yamanoi, T. Imai, T. Matsumoto, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>103.<\/td>\n<td>Enantiopure Acetals of a-Alkynyl Carbonyl Compounds: Organoaluminum-Mediated 1,2-Shift of Cobalt-Complexed Alkynyl Group with Concomitant Capture by a Nucleophile, <em>Synlett<\/em>, <strong>1997<\/strong>, 304\uff0d306, by K. Taya, T. Nagasawa, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>102.<\/td>\n<td>Synthesis of <em>C<\/em>-Aryl Glycosides, in &#8220;Preparative Carbohydrate Chemistry&#8221;, ed. by S. Hanessian, Marcel Dekker, New York, Chapt. 24, pp 527\uff0d542, by K. Suzuki and T. Matsumoto.<\/td>\n<\/tr>\n<tr>\n<td>101.<\/td>\n<td>Novel Migrating Group in 1,2-Anionotropic Reactions: Cobalt-Complexation Facilitates 1,2-Shift of Alkynyl Groups, <em>J. Am. Chem. Soc., <\/em><strong>118<\/strong>, 8949\uff0d8950 (1996), by T. Nagasawa, K. Taya, M. Kitamura, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>100.<\/td>\n<td>Total Synthesis of <em>C<\/em>-Glycosyl Naphthacenequinone Antibiotic, Galtamycinone, <em>Synlett, <\/em><strong>1996<\/strong>, 433\uff0d\uff0d434, by T. Matsumoto, H. Yamaguchi, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>99.<\/td>\n<td>Hydrozirconation of Allenyl Sulfide for Generating g-Thio-substituted Allylzirconium Species and its Reaction with Carbonyl Compounds, <em>Chem. Lett., <\/em><strong>1996<\/strong>, 231\uff0d232, by M. Chino, L. G. Hao, T. Matsumoto, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>98.<\/td>\n<td>Total Syntheses of BE-12406 A and Its C(8)-Vinyl Analog, <em>Heterocycles, <\/em><strong>42<\/strong>, 397\uff0d414 (1996), by T. Hosoya, E. Takashiro, Y. Yamamoto, T. Matsumoto, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>97.<\/td>\n<td>On the Stereochemistry of Aryl <em>C<\/em>-Glycosides: Unusual Behavior of Bis-TBDPS Protected Aryl <em>C<\/em>-Olivosides, <em>Tetrahedron Lett<\/em>., <strong>37<\/strong>, 637\uff0d640 (1996), by T. Hosoya, Y. Ohashi, T. Matsumoto, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>96.<\/td>\n<td>Stereoselective Synthesis of Cyclopropanes via Homoallylic Participation, <em>Bull. Chem. Soc. Jpn.<\/em>, <strong>69<\/strong>, 31\uff0d39 (1996), by T. Nagasawa, Y. Handa, Y. Onoguchi, and K. Suzuki.<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h2 id=\"1991-1995\">1991-1995\u5e74<\/h2>\n<table class=\"color\">\n<tbody>\n<tr>\n<td>95.<\/td>\n<td>Cobalt-Complexation Makes 2-(Alkynyl)propene a Good Ene Donor in Carbonyl\uff0dEne Reaction, <em>Synlett, <\/em><strong>1995<\/strong>, 1183\uff0d1186, by T. Nagasawa, M. Kitamura, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>94.<\/td>\n<td>Stereoselective Synthesis of a Cyclopropane-Containing Eicosanoid, <em>Synlett<\/em>, <strong>1995<\/strong>, 1023\uff0d1024, by T. Nagasawa, Y. Onoguchi, T. Matsumoto, and K. Suzuki<em>.<\/em><\/td>\n<\/tr>\n<tr>\n<td>93.<\/td>\n<td>Total Synthesis of the Gilvocarcins, <em>J. Synth. Org. Chem. Jpn., <\/em><strong>53<\/strong>, 1045\uff0d1054 (1995), by K. Suzuki, T. Matsumoto, and T. Hosoya.<\/td>\n<\/tr>\n<tr>\n<td>92.<\/td>\n<td>Total Synthesis of (\u00b1)-Furaquinocin D, <em>J. Am. Chem. Soc., <\/em><strong>117<\/strong>, 10757\uff0d10758 (1995), by T. Saito, M. Morimoto, C. Akiyama, T. Matsumoto, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>91.<\/td>\n<td><em>C<\/em>-Glycosylation\uff0dCycloaddition Approach to <em>C<\/em>-Glycosylated Juglones. Versatile Intermediates in Aryl <em>C<\/em>-Glycoside Synthesis,<em> Chem. Lett.<\/em>, <strong>1995<\/strong>, 677\uff0d678, by T. Matsumoto, T. Sohma, H. Yamaguchi, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>90.<\/td>\n<td>Stereoselective Synthesis of Cyclopropanes via Homoallylic Participation, <em>Synlett<\/em>, <strong>1995<\/strong>, 731\uff0d736, by T. Nagasawa, Y. Handa, Y. Onoguchi, S. Ohba, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>89.<\/td>\n<td>Total Synthesis of Antibiotic C104: Benzyne\uff0dFuran Cycloaddition Approach to the Angucyclines, <em>Tetrahedron, <\/em><strong>51<\/strong>, 7347\uff0d7360 (1995), by T. Matsumoto, T. Sohma, S. Kurata, H. Yamaguchi, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>88.<\/td>\n<td>Convenient Synthesis of Phthalides via Regioselective Baeyer\uff0dVilliger Oxidation of Benzocyclobutenones, <em>Synlett, <\/em><strong>1995<\/strong>, 635\uff0d638<em>, <\/em>by T. Hosoya, Y. Kuriyama, T. Matsumoto, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>87.<\/td>\n<td>Stereospecificity in [2 + 2] Cycloaddition of Benzyne and Ketene Silyl Acetal, <em>Tetrahedron Lett.,<\/em> <strong>36<\/strong>, 3377\uff0d3380 (1995), by T. Hosoya, T. Hasegawa, Y. Kuriyama, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>86.<\/td>\n<td>AgAsF6 as Safe Alternative to AgClO<sub>4<\/sub> for Generating Cationic Zirconocene Complexes: Utilities in Selective C\uff0dC Bond Forming Reactions, <em>Tetrahedron<\/em>, <strong>55<\/strong>, 4483\uff0d4494 (1995), by K. Suzuki, T. Hasegawa, T. Imai, H. Maeta, and S. Ohba.<\/td>\n<\/tr>\n<tr>\n<td>85.<\/td>\n<td>Benzyne\uff0dFuran Cycloaddition Approach to the Angucyclines: Total Synthesis of Antibiotic C104, <em>Synlett, <\/em><strong>1995<\/strong>, 263\uff0d266, by T. Matsumoto, T. Sohma, S. Kurata, H. Yamaguchi, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>84.<\/td>\n<td>[2 + 2] Cycloaddition of Benzyne and Ketene Silyl Acetal as an Efficient Route to Benzocyclobutenones, <em>Synlett, <\/em><strong>1995<\/strong>, 177\uff0d179, by T. Hosoya, T. Hasegawa, Y. Kuriyama, T. Matsumoto, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>83.<\/td>\n<td>Unexpected Outcome of NbCl<sub>5<\/sub>-Promoted Sakurai Reaction: Mechanistic Implication Relevant to C<sub>4<\/sub>H<sub>7<\/sub>+ Species, <em>Tetrahedron Lett., <\/em><strong>36<\/strong>, 899\uff0d902 (1995), by H. Maeta, T. Nagasawa, Y. Handa, T. Takei, Y. Osamura, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>82.<\/td>\n<td>Total Synthesis of Aryl <em>C<\/em>-Glycoside Antibiotics, <em>Pure Appl. Chem., <\/em><strong>66<\/strong>, 2175\uff0d2178 (1994) by K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>81.<\/td>\n<td>First Total Synthesis of BE-12406 A, <em>Tetrahedron Lett., <\/em><strong>35<\/strong>, 4591\uff0d4594 (1994), by T. Hosoya, E. Takashiro, T. Matsumoto, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>80.<\/td>\n<td>Novel Lewis Acid Catalysis in Organic Synthesis, <em>Pure Appl. Chem., <\/em><strong>66<\/strong>, 1557\uff0d1564 (1994), by K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>79.<\/td>\n<td>Convenient Procedure for Selective Generation of Allylzirconocene Chlorides via Hydrozirconation of Allenes, <em>Synlett, <\/em><strong>1994<\/strong>, 359\uff0d363, by M. Chino, T. Matsumoto, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>78.<\/td>\n<td>Total Syntheses of the Gilvocarcins, <em>J. Am. Chem. Soc., <\/em><strong>116<\/strong>, 1004\uff0d1015 (1994), by T. Hosoya, E. Takashiro, T. Matsumoto, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>77.<\/td>\n<td>On the Regiochemistry of Cycloaddition of Unsymmetrical Aryne with Nitrone. Remarkable Effect of Trialkylsilyl Substituent, <em>Synlett, <\/em><strong>1993<\/strong>, 843\uff0d846, by T. Matsumoto, T. Sohma, S. Hatazaki, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>76.<\/td>\n<td>New Methods in Glycoside Synthesis by Using Early Transition Metal-Derived Reagent, <em>J. Synth. Chem. Soc. Jpn., <\/em><strong>51<\/strong>, 718\uff0d732 (1993), by K. Suzuki and T. Matsumoto.<\/td>\n<\/tr>\n<tr>\n<td>75.<\/td>\n<td>&#8220;Dibutyltin Diperchlorate&#8221; for Activation of Glycosyl Fluoride, <em>Carbohydr. Res.<\/em>, <strong>249<\/strong>, 49\uff0d56 (1993), by H. Maeta, T. Matsumoto, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>74.<\/td>\n<td>Total Synthesis of Aryl <em>C<\/em>-Glycoside Antibiotics<em>, <\/em>In &#8220;Recent Progress in the Chemical Synthesis of Antibiotics and Related Microbial Products&#8221;, Vol. 2., G. Lukacs ed, Springer Verlag, pp 352\uff0d403, by K. Suzuki and T. Matsumoto.<\/td>\n<\/tr>\n<tr>\n<td>73.<\/td>\n<td>Hydrozirconation of Allenylstannane for Generating Three-Carbon Bimetallic Species: Synthesis of (<em>E<\/em>)-1,3-Dienes from Carbonyl Compounds, <em>Synlett<\/em>, <strong>1993<\/strong>, 341\uff0d343, by H. Maeta, T. Hasegawa, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>72.<\/td>\n<td>[3+1] Synthetic Route toward Cyclobutane\/butene Derivatives Utilizing Large a-Cation-Stabilizing Effect of Cyclopropane, <em>Synlett<\/em>, <strong>1993<\/strong>, 29\uff0d31, by T. Nagasawa and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>71.<\/td>\n<td>Two- and Four-Carbon Homologation of Aldehyde by AgClO<sub>4<\/sub>-Catalyzed Addition of Alkoxyalkenylzirconocene Chloride, <em>Tetrahedron Lett., <\/em><strong>34<\/strong>, 341\uff0d344 (1993), by H. Maeta and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>70.<\/td>\n<td>Specific Interaction between Lewis Acid and Organic Substrate Can Offer New Reactivities and Selectivities in Organic Synthesis, in <em>&#8220;Organic Synthesis in Japan, Past, Present, and Future&#8221;<\/em>, <em>J. Synth. Chem. Soc. Jpn., 50th Anniversary Special Ed<\/em>. (R. Noyori Ed.), pp 425\uff0d432, by K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>69.<\/td>\n<td>New and Highly (<em>E<\/em>)-Selective Synthesis of Terminal 1,3-Diene via Three-Carbon Elongation of Aldehyde, <em>Tetrahedron Lett.<\/em>, <strong>33<\/strong>, 5969\uff0d5972 (1992), by H. Maeta and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>68.<\/td>\n<td>Grignard-type Reactivity of Alkenyl and Alkylzirconocene Chloride to Aldehyde: Remarkable Catalytic Acceleration Effect of AgClO<sub>4<\/sub>, <em>Tetrahedron Lett.<\/em>, <strong>33<\/strong>, 5965\uff0d5968 (1992), by H. Maeta, T. Hashimoto, T. Hasegawa, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>67.<\/td>\n<td><em>trans<\/em>-1,3-Bis(diphenylphosphinoyl)cyclohexane, <em>Acta Cryst.<\/em>, <strong>C48<\/strong>, 1710\uff0d1712 (1992), by M. Morooka, T. Hashimoto, H. Meta, T. Matsumoto, K. Suzuki, and S. Ohba.<\/td>\n<\/tr>\n<tr>\n<td>66.<\/td>\n<td>Recent Progress in <em>O<\/em>-Glycoside Synthesis. Methodological Aspects, <em>J. Synth. Chem. Soc. Jpn., <\/em><strong>50<\/strong><em>, <\/em>378\uff0d390 (1992), by K. Suzuki, T. Nagasawa.<\/td>\n<\/tr>\n<tr>\n<td>65.<\/td>\n<td>Total Synthesis and Absolute Stereochemical Assignment of (+)-Gilvocarcin M, <em>J. Am. Chem. Soc., <\/em><strong>114<\/strong>, 3568\uff0d3570 (1992), by T. Matsumoto, T. Hosoya, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>64.<\/td>\n<td>Synthesis of 1,3-Bis(diphenylphosphinoyl)alkanes via Double Addition of Diphenylphosphine to a,b-Unsaturated Carbonyl Compounds. Sequential 1,4- and 1,2-Addition Promoted by NbCl<sub>5<\/sub>\uff0dBF<sub>3<\/sub>\uff0dOEt<sub>2<\/sub>, <em>Synlett<\/em>, <strong>1992<\/strong>, 340\uff0d342, by T. Hashimoto, H. Maeta, T. Matsumoto, M. Morooka, S. Ohba, and K. Suzuki<\/td>\n<\/tr>\n<tr>\n<td>63.<\/td>\n<td><em>threo<\/em>-3-Alkyl- and -Aryl-glutamic Acid Derivatives by Michael Additions of Boc-BMI Li-Enolates to 2,6-Di-<em>t<\/em>-butyl-4-methoxyphenyl Alkenoates. On the Diastereoselectivity of Coupling of Trigonal Centers Involving Heterocyclic Li-Enolates, <em>Liebigs Ann. Chem.<\/em>, <strong>1992<\/strong>, 51\uff0d61, by K. Suzuki and D. Seebach.<\/td>\n<\/tr>\n<tr>\n<td>62.<\/td>\n<td>An Alternative Synthetic Route to the C(11)-C(17) Fragment of Mycinolide IV, <em>Synlett, <\/em><strong>1992<\/strong>, 129\uff0d130, by K. Tomooka, K. Matsumoto, K. Suzuki, and G. Tsuchihashi.<\/td>\n<\/tr>\n<tr>\n<td>61.<\/td>\n<td>Lewis Acid-Promoted Reaction of Secondary Phosphines with Carbonyl Compounds: Remarkable Effect of NbCl<sub>5<\/sub> in Promoting Intramolecular Oxidation\uff0dReduction Process, <em>Synlett<\/em>, <strong>1992<\/strong>, 125\uff0d128, by K. Suzuki, T. Hashimoto, H. Maeta, and T. Matsumoto.<\/td>\n<\/tr>\n<tr>\n<td>60.<\/td>\n<td>New Efficient Protocol for Aryne Generation. Selective Synthesis of Differentially Protected 1,4,5-<br \/>\nNaphthalenetriols, <em>Tetrahedron Lett<\/em>., <strong>32<\/strong>, 6735 (1991). by T. Matsumoto, T. Hosoya, M. Katsuki, K. Suzuki,<\/td>\n<\/tr>\n<tr>\n<td>59.<\/td>\n<td><em>O\uff0dC-<\/em>Glycoside Rearrangement of Resorcinol Derivatives. Versatile Intermediates in the Synthesis of Aryl <em>C<\/em>-Glycosides, <em>Synlett<\/em>, <strong>1991<\/strong>, 709\uff0d712, by T. Matsumoto, T. Hosoya, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>58.<\/td>\n<td>Efficient Method for Introducing Vineomycin\uff0dFridamycin-Type Side Chain. Total Synthesis of Fridamycin E, <em>Tetrahedron Lett.<\/em>, <strong>32<\/strong>, 5103\uff0d5106 (1991), by T. Matsumoto, H. Jona, M. Katsuki, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>57.<\/td>\n<td><em>Ortho<\/em>-Metallation of Anthracene Derivative: Problem and Solution, <em>Tetrahedron Lett., <\/em><strong>32<\/strong>, 4337\uff0d4340 (1991), by T. Matsumoto, H. Kakigi, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>56.<\/td>\n<td>Convergent Total Synthesis of Vineomycinone B&lt;sub&gt;2&lt;\/sub&gt; Methyl Ester and Its C(12)-Epimer, <em>J. Am. Chem. Soc.<\/em>, <strong>113<\/strong>, 6982\uff0d6992 (1991), by T. Matsumoto, M. Katsuki, H. Jona, and K. Suzuki.<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h2 id=\"1986-1990\">1986-1990\u5e74<\/h2>\n<table class=\"color\">\n<tbody>\n<tr>\n<td>55.<\/td>\n<td>Improvement in <em>O<\/em>\uff0d<em>C<\/em>-Glycoside Rearrangement Approach to <em>C<\/em>-Glycosides: Use of 1-<em>O<\/em>-Acetyl Sugar as Stable but Efficient Glycosyl Donor, <em>Tetrahedron Lett., <\/em><strong>31<\/strong><em>,<\/em> 4629\uff0d4632 (1990)<em>, <\/em>by T. Matsumoto, T. Hosoya, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>54.<\/td>\n<td>Cp<sub>2<\/sub>MCl<sub>2<\/sub>\uff0dAgX (M=Zr, Hf): A Reagent for Glycosidation, <em>J. Synth. Chem. Soc., Jpn.<\/em>, <strong>48<\/strong>, 1026\uff0d1027 (1990), by K. Suzuki and T. Matsumoto.<\/td>\n<\/tr>\n<tr>\n<td>53.<\/td>\n<td>Recent Development in Glycosylation Reaction, <em>Chemistry and Chemical Industry, <\/em><strong>43<\/strong>, 918\uff0d921 (1990), by K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>52.<\/td>\n<td>Stereoselective Construction of Three- and Four-Contiguous Asymmetric Centers: A novel Possibility by Alkylative Rearrangement of Epoxy Silyl Ethers, <em>Tetrahedron Lett<\/em>., <strong>31<\/strong><em>,<\/em> 3335\uff0d3338 (1990), by M. Shimazaki, M. Morimoto, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>51.<\/td>\n<td>4-<em>O<\/em>-Benzyl-2,3-<em>O<\/em>-isopropylidene-L-threose: A Useful Building Block for Stereoselective Synthesis of Monosaccharides, <em>Tetrahedron<\/em>, <strong>46<\/strong>, 265\uff0d276 (1990), by T. Mukaiyama, K. Suzuki, T. Yamada, and F. Tabusa.<\/td>\n<\/tr>\n<tr>\n<td>50.<\/td>\n<td>Cp<sub>2<\/sub>ZrCl<sub>2<\/sub>\uff0dAgBF<sub>4<\/sub> in Benzene: Reagent System for Rapid and Highly a-Selective Glycosidation of Tetra-<em>O<\/em>-benzyl-D-mannopyranosyl Fluoride, <em>Tetrahedron Lett<\/em>., <strong>30<\/strong><em>,<\/em> 6879\uff0d6882 (1989), by K. Suzuki, H. Maeta, T. Suzuki, and T. Matsumoto.<\/td>\n<\/tr>\n<tr>\n<td>49.<\/td>\n<td>Synthetic Study toward Vineomycins. Synthesis of <em>C<\/em>-Aryl Glycoside Sector via Cp<sub>2<\/sub>HfCl<sub>2<\/sub>\uff0dAgClO<sub>4<\/sub>-Promoted Tactics to <em>C<\/em>-Aryl Glycoside Synthesis, <em>Tetrahedron Lett<\/em>., <strong>30<\/strong><em>,<\/em> 6185\uff0d6188 (1989), by T. Matsumoto, M. Katsuki, H. Jona, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>48.<\/td>\n<td>Stereoselective Reduction of a-Cyclopropyl Ketones and a-Cyclopropyl Aldols. Stereo-directing Effect by Trimethylsilyl Group, <em>Tetrahedron Lett.<\/em>, <strong>30<\/strong>, 5447\uff0d5450 (1989), by M. Shimazaki, H. Hara, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>47.<\/td>\n<td>Stereospecific 1,2-Rearrangement of Cyclopropyl Group. Synthesis of Chiral a-Cyclopropyl Ketones and a-Cyclopropyl Aldols, <em>Tetrahedron Lett<\/em>, <strong>30<\/strong>, 5443\uff0d5446 (1989), by M. Shimazaki, H. Hara, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>46.<\/td>\n<td>An Improved Procedure for Metallocene-Promoted Glycosidation. Enhanced Reactivity by Use of 1:2-Ratio of Cp<sub>2<\/sub>HfCl<sub>2<\/sub>-AgClO<sub>4<\/sub>, <em>Tetrahedron Lett<\/em>, <strong>30<\/strong>, 4853\uff0d4856 (1989), by K. Suzuki, H. Maeta, and T. Matsumoto.<\/td>\n<\/tr>\n<tr>\n<td>45.<\/td>\n<td>Lactols in Stereoselection 3. Highly <em>anti<\/em>-Cram Selective 1,2-Asymmetric Induction, <em>Tetrahedron Lett.<\/em>, <strong>30<\/strong>, 1563\uff0d1566 (1989), by K. Tomooka, T. Okinaga, K. Suzuki, and G. Tsuchihashi.<\/td>\n<\/tr>\n<tr>\n<td>44.<\/td>\n<td>Rapid <em>O<\/em>-Glycosidation of Phenols with Glycosyl Fluoride by Using the Combinational Activator, Cp<sub>2<\/sub>HfCl<sub>2<\/sub> and AgClO<sub>4<\/sub>, <em>Chem. Lett<\/em>., <strong>1989<\/strong>, 437\uff0d440, by T. Matsumoto, M. Katsuki, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>43.<\/td>\n<td>Cp<sub>2<\/sub>ZrCl<sub>2<\/sub>\uff0dAgClO<sub>4<\/sub>: Efficient Promoter in the Friedel\uff0dCrafts Approach to <em>C<\/em>-Aryl Glycosides, <em>Tetrahedron Lett.<\/em>, <strong>30<\/strong>, 833\uff0d836 (1989), by T. Matsumoto, M. Katsuki, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>42.<\/td>\n<td>New Approach to <em>C<\/em>-Aryl Glycosides Starting from Phenol and Glycosyl Fluoride. Lewis Acid-Catalyzed Rearrangement of <em>O<\/em>-Glycoside to <em>C<\/em>-Glycoside, <em>Tetrahedron Lett<\/em>., <strong>29<\/strong>, 6935\uff0d6938 (1988), by T. Matsumoto, M. Katsuki, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>41.<\/td>\n<td>First Total Synthesis of Mycinamicin IV and VII. Successful Application of New Glycosidation Reaction, <em>Tetrahedron Lett<\/em>., <strong>29,<\/strong> 3575\uff0d3578 (1988), by T. Matsumoto, H. Maeta, K. Suzuki, and G. Tsuchihashi.<\/td>\n<\/tr>\n<tr>\n<td>40.<\/td>\n<td>New Glycosidation Reaction 2. Preparation of 1-Fluoro-D-Desosamine Derivative and its Efficient Glycosidation by the Use of Cp<sub>2<\/sub>HfCl<sub>2<\/sub>\uff0dAgClO<sub>4<\/sub> as the Activator, <em>Tetrahedron Lett.,<\/em> <strong>29<\/strong>, 3571\uff0d3574 (1988), by K. Suzuki, H. Maeta, T. Matsumoto, and G. Tsuchihashi.<\/td>\n<\/tr>\n<tr>\n<td>39.<\/td>\n<td>New Glycosidation Reaction 1. Combinational Use of Cp<sub>2<\/sub>HfCl<sub>2<\/sub>\uff0dAgClO<sub>4<\/sub> for Activation of Glycosyl Fluorides and Application to Highly b-Selective Glycosidation of D-Mycinose, <em>Tetrahedron Lett.<\/em>, <strong>29<\/strong>, 3567\uff0d3570 (1988), by T. Matsumoto, H. Maeta, K. Suzuki, and G. Tsuchihashi.<\/td>\n<\/tr>\n<tr>\n<td>38.<\/td>\n<td>Silicon-Directed Stereoselective Synthesis of 2-Vinyl-1,3-diols. Stereodivergence with and without the Silyl Group Related to the Synthesis of Avenaciolide and Isoavenaciolide, <em>Tetrahedron<\/em>, <strong>44<\/strong>, 4061\uff0d4072 (1988), by K. Suzuki, M. Miyazawa, M. Shimazaki, and G. Tsuchihashi.<\/td>\n<\/tr>\n<tr>\n<td>37.<\/td>\n<td>Highly Selective Acyclic Stereocontrol Based on 1,2-Rearrangement, <em>J. Synth. Org. Chem. Jpn<\/em>., <strong>46<\/strong>, 365\uff0d377 (1988), by K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>36.<\/td>\n<td>Lactols in Stereoselection 2. Stereoselective Synthesis of Disubstituted Cyclic Ethers, <em>Tetrahedron Lett.,<\/em> <strong>28<\/strong>, 6339\uff0d6342 (1987), by K. Tomooka, K. Matsuzawa, K. Suzuki, and G. Tsuchihashi.<\/td>\n<\/tr>\n<tr>\n<td>35.<\/td>\n<td>Lactols in Stereoselection 1. Highly Selective 1,4- and 1,5-Asymmetric Induction, <em>Tetrahedron Lett.<\/em>, <strong>28<\/strong>, 6335\uff0d6338 (1987), by K. Tomooka, T. Okinaga, K. Suzuki, and G. Tsuchihashi.<\/td>\n<\/tr>\n<tr>\n<td>34.<\/td>\n<td>On the Use of Epoxy Alcohol-Aldol Rearrangement for the Stereocontrol of Quaternary Carbon Centers, <em>Tetrahedron Lett.<\/em>, <strong>28<\/strong>, 5891\uff0d5894 (1987), by M. Shimazaki, H. Hara, K. Suzuki, and G. Tsuchihashi.<\/td>\n<\/tr>\n<tr>\n<td>33.<\/td>\n<td>Catalytic Version of Epoxy Silyl Rearrangements, <em>Tetrahedron Lett.,<\/em> <strong>28<\/strong>, 3515\uff0d3518 (1987), by K. Suzuki, M. Miyazawa, and G. Tsuchihashi.<\/td>\n<\/tr>\n<tr>\n<td>32.<\/td>\n<td>Two-Carbon Homologation of Amides with Lithium (Triphenylsilyl)acetylide, <em>J. Org. Chem.<\/em>, <strong>52<\/strong>, 2929\uff0d2930 (1987), by K. Suzuki, T. Ohkuma, and G. Tsuchihashi.<\/td>\n<\/tr>\n<tr>\n<td>31.<\/td>\n<td>Stereocontrolled First Total Synthesis of Mycinolide IV, <em>Chem. Lett.<\/em>, <strong>1987<\/strong>, 113\uff0d116, by K. Suzuki, T. Matsumoto, K. Tomooka, K. Matsumoto, and G. Tsuchihashi.<\/td>\n<\/tr>\n<tr>\n<td>30.<\/td>\n<td>Stereo-Divergent Asymmetric Total Synthesis of Avenaciolide and Isoavenaciolide. Complete Reversal of Stereoselectivity in Reduction of 2-Vinyl Aldols with \/ without Trimethylsilyl Directing Group, <em>Tetrahedron Lett.<\/em>, <strong>27<\/strong>, 6237\uff0d6240 (1986), by K. Suzuki, M. Miyazawa, M. Shimazaki, and G. Tsuchihashi.<\/td>\n<\/tr>\n<tr>\n<td>29.<\/td>\n<td>Synthesis of 2-Vinyl-1,3-diols via Highly Stereoselective Reduction of 2-Vinyl Aldols using Trimethylsilyl Group as Stereo-Directing Group, <em>Tetrahedron Lett.<\/em>, <strong>27<\/strong>, 6233\uff0d6336 (1986), by K. Suzuki, M. Shimazaki, and G, Tsuchihashi.<\/td>\n<\/tr>\n<tr>\n<td>28.<\/td>\n<td>Stereocontrolled Asymmetric Total Synthesis of Protomycinolide IV, <em>J. Am. Chem. Soc.<\/em>, <strong>108<\/strong>, 5221\uff0d5229 (1986), by K. Suzuki, K. Tomooka, E. Katayama, T. Matsumoto, and G. Tsuchihashi.<\/td>\n<\/tr>\n<tr>\n<td>27.<\/td>\n<td>C(2)-Stereocontrol of d-Lactones via Acid-Catalyzed Cyclization of Ketene Dithioacetal Having an Internal Hydroxyl Group, <em>Tetrahedron Lett<\/em>., <strong>27<\/strong>, 3661\uff0d3664 (1986), by K. Suzuki, T. Masuda, Y. Fukazawa, and G. Tsuchihashi.<\/td>\n<\/tr>\n<tr>\n<td>26.<\/td>\n<td>Epoxy Silyl Ether Rearrangements: A New, Stereoselective Approach to the Synthesis of b-Hydroxy Carbonyl Compounds, <em>J. Am. Chem. Soc.<\/em>, <strong>108<\/strong>, 3827\uff0d3829 (1986), by K. Maruoka, M. Hasegawa, H. Yamamoto, K. Suzuki, M. Shimazaki, and G. Tsuchihashi.<\/td>\n<\/tr>\n<tr>\n<td>25.<\/td>\n<td>Asymmetric Synthesis of Chiral Synthons Bearing Alkynyl Group via Organoaluminum-Promoted Pinacol-Type Rearrangement, <em>Tetrahedron Lett.<\/em>, <strong>27<\/strong>, 373\uff0d376 (1986), by K. Suzuki, T. Ohkuma, M. Miyazawa, and G. Tsuchihashi.<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h2 id=\"1978-1985\">1978-1985\u5e74<\/h2>\n<table class=\"color\">\n<tbody>\n<tr>\n<td>24.<\/td>\n<td>Conformational Effects in Organoaluminum-Promoted Pinacol-Type Rearrangement, <em>Tetrahedron Lett.<\/em>, <strong>26<\/strong>, 4781\uff0d4784 (1985), by K. Suzuki, K. Tomooka, M. Shimazaki, and G. Tsuchihashi.<\/td>\n<\/tr>\n<tr>\n<td>23.<\/td>\n<td>Stereoselective Synthesis of C(1)-C(9) and C(11)-C(17) Fragments of Protomycinolide IV Based on Asymmetric Pinacol-Type Rearrangement, <em>Tetrahedron Lett.<\/em>, <strong>26,<\/strong> 3711\uff0d3714 (1985), by K. Suzuki, K. Tomooka, T. Matsumoto, E. Katayama, and G. Tsuchihashi.<\/td>\n<\/tr>\n<tr>\n<td>22.<\/td>\n<td>Highly Stereoselective Approach to Chiral Building Block Possessing Three Contiguous Asymmetric Centers. Preparation of Four Possible Diastereomers of b,b&#8217;-Dimethyl-bis-homoallylic Alcohol Derivative, <em>Tetrahedron Lett.<\/em>, <strong>26<\/strong>, 3707\uff0d3710 (1985), by K. Suzuki, E. Katayama, K. Tomooka, T. Matsumoto, and G. Tsuchihashi.<\/td>\n<\/tr>\n<tr>\n<td>21.<\/td>\n<td>Enantio- and Diastereo-Controlled Synthesis of (+)- and (\uff0d)-Eldanolide Based on Asymmetric Pinacol-Type Rearrangement, <em>Tetrahedron Lett.<\/em>, <strong>26<\/strong>, 861\uff0d864 (1985), by K. Suzuki, T. Ohkuma, and G. Tsuchihashi.<\/td>\n<\/tr>\n<tr>\n<td>20.<\/td>\n<td>Completely Stereospecific 1,2-Migration of Alkyl Groups in Et<sub>2<\/sub>AlCl Promoted Pinacol-Type Rearrangement, <em>Tetrahedron Lett.,<\/em> <strong>25<\/strong>, 4253\uff0d4256 (1984), by G. Tsuchihashi, K. Tomooka, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>19.<\/td>\n<td>Reductive Pinacol-Type Rearrangement of a-Mesyloxy Ketones Promoted by Organoaluminum Compounds, <em>Tetrahedron Lett<\/em>., <strong>25<\/strong>, 3715\uff0d3718 (1984), by K. Suzuki, E. Katayama, T. Matsumoto, and G. Tsuchihashi.<\/td>\n<\/tr>\n<tr>\n<td>18.<\/td>\n<td>Enantio- and Diastereomerically Pure <em>threo<\/em>-Homoallylic Alcohols via Highly Stereoselective Reduction of a-Methyl-b,g-unsaturated Ketones, <em>Tetrahedron Lett.<\/em>, <strong>25<\/strong>, 2479-2482 (1984), by K. Suzuki, E. Katayama, and G. Tsuchihashi.<\/td>\n<\/tr>\n<tr>\n<td>17.<\/td>\n<td>Asymmetric Synthesis of Optically Pure a-Methyl-b,g-unsaturated Ketones via Triethylaluminum-Mediated Stereospecific Pinacol Rearrangement of Alkenyl Groups, <em>Tetrahedron Lett.<\/em>, <strong>25,<\/strong> 1817\uff0d1820 (1984), by K. Suzuki, E. Katayama, and G. Tsuchihashi.<\/td>\n<\/tr>\n<tr>\n<td>16.<\/td>\n<td>A Formal Total Synthesis of Polyoxin J Using 4-<em>O<\/em>-Benzyl-2,3-<em>O<\/em>-isopropyliden-L-threose as a Common Chiral Building Block, <em>Chem. Lett.<\/em>, <strong>1984<\/strong>, 405\uff0d\uff0d408, by F. Tabusa, T. Yamada, K. Suzuki, and T. Mukaiyama.<\/td>\n<\/tr>\n<tr>\n<td>15.<\/td>\n<td>Asymmetric Pinacol-Type Rearrangement of a-Hydroxy Methanesulfonates Promoted by Triethylaluminum. Preparation of Optically Pure a-Aryl and a-Vinyl Ketones, <em>Tetrahedron Lett.<\/em>, <strong>24<\/strong>, 4997\uff0d5000 (1983), by K. Suzuki, E. Katayama, and G. Tsuchihashi.<\/td>\n<\/tr>\n<tr>\n<td>14.<\/td>\n<td>The Stereoselective Synthesis of 2,3-cis-Dihydroxy-g-butyrolactones by Oxidation of g-Butenolide with KMnO4-Crown Ether, <em>Chem. Lett<\/em>., <strong>1983<\/strong>, 173\uff0d174, by T. Mukaiyama, F. Tabusa, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>13.<\/td>\n<td>Stereoselective Synthesis of L-Sugars of Biological Importance Starting from 4-<em>O<\/em>-Benzyl-2,3-<em>O<\/em>-isopropylidene-L-threose as a Chiral Building Block, <em>Chem. Lett.<\/em>, <strong>1983<\/strong>, 5\uff0d8, by T. Mukaiyama, T. Yamada, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>12.<\/td>\n<td>The Enantioselective Michael Addition of Thiols to Cycloalkenones Using (2<em>S<\/em>,4<em>S<\/em>)-2-Anilinomethyl-1-ethyl-4-hydroxypyrrolidine as Chiral Catalyst, <em>Bull. Chem. Soc. Jpn.<\/em>, <strong>55<\/strong>, 3277\uff0d3282 (1982), by K. Suzuki, A. Ikegawa, and T. Mukaiyama.<\/td>\n<\/tr>\n<tr>\n<td>11.<\/td>\n<td>Highly Stereoselective Synthesis of a-D-Glucopyranosides by the <em>N<\/em>-Iodosuccinimide-promoted Internal Cyclization, <em>Chem. Lett.,<\/em> <strong>1982<\/strong>, 1525\uff0d1528, by K. Suzuki and T. Mukaiyama.<\/td>\n<\/tr>\n<tr>\n<td>10.<\/td>\n<td>The Stereoselective Synthesis of L-Tagatose. An Application of Zn(II)-Mediated Highly Stereoselective Addition of 2-Furyllithium to Polyoxygenated Aldehyde, <em>Chem. Lett.<\/em>, <strong>1982<\/strong>, 1169\uff0d1170, by T. Mukaiyama, Y. Yuki, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>9.<\/td>\n<td>4-<em>O<\/em>-Benzyl-2,3-<em>O<\/em>-isopropylidene-L-threose. A New and Useful Building Block for the Synthesis of L-Sugars, <em>Chem. Lett<\/em>., <strong>1982<\/strong>, 929\uff0d932, by T. Mukaiyama, K. Suzuki, and T. Yamada.<\/td>\n<\/tr>\n<tr>\n<td>8.<\/td>\n<td>Asymmetric Synthesis of Optically Active Cyclohexenol Derivatives via Highly Stereoselective Reduction of (<em>R<\/em>)-3-(<em>p<\/em>&#8211;<em>t<\/em>-Butylphenylthio)cyclohexan-1-one, <em>Chem. Lett.<\/em>, <strong>1982<\/strong>, 899\uff0d892, by K. Suzuki, A. Ikegawa, and T. Mukaiyama.<\/td>\n<\/tr>\n<tr>\n<td>7.<\/td>\n<td>A Novel Method for the Synthesis of 2-Deoxydisaccharide by Stereoselective Cyclization of the Acyclic Precursor, <em>Chem. Lett.<\/em>, <strong>1981<\/strong>, 683\uff0d686, by K. Suzuki and T. Mukaiyama.<\/td>\n<\/tr>\n<tr>\n<td>6.<\/td>\n<td>The Stereoselective Synthesis of D-Ribulose, <em>Chem. Lett.<\/em>, <strong>1981<\/strong>, 1529\uff0d1532, by K. Suzuki, Y. Yuki, and T. Mukaiyama.<\/td>\n<\/tr>\n<tr>\n<td>5.<\/td>\n<td>Highly Enantioselective Michael Addition of Thiols to 2-Cyclohexenone by Using (2<em>S,<\/em>4<em>S<\/em>)-2-(Anilinomethyl)-1-ethyl-4-hydroxypyrrolidine as a Chiral Catalyst, <em>Chem. Lett.<\/em>, <strong>1981<\/strong>, 165\uff0d168, by T. Mukaiyama, A. Ikegawa, and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>4.<\/td>\n<td>Asymmetric Addition of Acetylide to Aliphatic Aldehydes. Preparation of Optically Active 5-Octyl-2(5H)-furanone, <em>Chem. Lett.<\/em>, <strong>1980<\/strong>, 255\uff0d256, by T. Mukaiyama and K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>3.<\/td>\n<td>Enantioselective Addition of Acetylene to Aldehyde. Preparation of Optically Active Alkynyl Alcohols, <em>Chem. Lett.<\/em>, <strong>1979<\/strong><em>,<\/em> 447\uff0d448, by T. Mukaiyama, K. Suzuki, K. Soai, and T. Sato.<\/td>\n<\/tr>\n<tr>\n<td>2.<\/td>\n<td>Enantioface-Differentiating (Asymmetric) Addition of Alkyllithium and Dialkylmagnesium to Aldehydes by Using (2<em>S<\/em>, 2&#8242;<em>S<\/em>)-2-Hydroxymethyl-1-[(1-alkylpyrrolidin-2-yl)methyl]pyrrolidine as Chiral Ligands, <em>J. Am. Chem. Soc<\/em>., <strong>101<\/strong>, 1455-1460 (1979), by T. Mukaiyama, K. Soai, T. Sato, H. Shimizu, K. Suzuki.<\/td>\n<\/tr>\n<tr>\n<td>1.<\/td>\n<td>Enantioface-Differentiating (Asymmetric) Addition of Dialkylmagnesium to Aldehydes by Using (2<em>S<\/em>, 2&#8242;<em>S<\/em>)-2-Hydroxymethyl-1-[(1-alkylpyrrolidin-2-yl)methyl]pyrrolidine as a Chiral Ligands, <em>Chem. Lett.<\/em>, <strong>1978<\/strong>, 601-604, by T. Sato, K. Soai, K. Suzuki, T. Mukaiyama.<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n","protected":false},"excerpt":{"rendered":"<p>2021\u5e74\u4ee5\u964d 2016-2020\u5e74 2011-2015\u5e74 2006-2010\u5e74 2001-2005\u5e74 1996-2000\u5e74 1991-1995\u5e74 1986-1990\u5e74 1978-1985\u5e74 \u8457 \u66f8 1996-2000\u5e74 [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"page.php","meta":{"_exactmetrics_skip_tracking":false,"_exactmetrics_sitenote_active":false,"_exactmetrics_sitenote_note":"","_exactmetrics_sitenote_category":0,"footnotes":""},"class_list":["post-66","page","type-page","status-publish","hentry"],"aioseo_notices":[],"_links":{"self":[{"href":"https:\/\/www.org-synth.chem.sci.titech.ac.jp\/index.php?rest_route=\/wp\/v2\/pages\/66","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.org-synth.chem.sci.titech.ac.jp\/index.php?rest_route=\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/www.org-synth.chem.sci.titech.ac.jp\/index.php?rest_route=\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/www.org-synth.chem.sci.titech.ac.jp\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.org-synth.chem.sci.titech.ac.jp\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=66"}],"version-history":[{"count":3,"href":"https:\/\/www.org-synth.chem.sci.titech.ac.jp\/index.php?rest_route=\/wp\/v2\/pages\/66\/revisions"}],"predecessor-version":[{"id":1995,"href":"https:\/\/www.org-synth.chem.sci.titech.ac.jp\/index.php?rest_route=\/wp\/v2\/pages\/66\/revisions\/1995"}],"wp:attachment":[{"href":"https:\/\/www.org-synth.chem.sci.titech.ac.jp\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=66"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}