{"id":41,"date":"2016-10-27T23:05:58","date_gmt":"2016-10-27T14:05:58","guid":{"rendered":"https:\/\/www.org-synth.chem.sci.titech.ac.jp\/ohmorilab\/wordpress\/?page_id=41"},"modified":"2017-07-13T21:14:37","modified_gmt":"2017-07-13T12:14:37","slug":"%e6%96%b0%e5%8f%8d%e5%bf%9c%e3%81%ae%e9%96%8b%e7%99%ba","status":"publish","type":"page","link":"https:\/\/www.org-synth.chem.sci.titech.ac.jp\/?page_id=41","title":{"rendered":"\u65b0\u53cd\u5fdc\u306e\u958b\u767a"},"content":{"rendered":"<h3 style=\"text-align: left;\">\u3000\u8907\u96d1\u306a\u5206\u5b50\u306e\u5408\u6210\u306f\u3001\u3072\u3068\u3064\u306e\u53cd\u5fdc\u3092\u6975\u3081\u305f\u3060\u3051\u3067\u306f\u9054\u6210\u3067\u304d\u307e\u305b\u3093\u3002\u5408\u6210\u6226\u7565\u3068\u6226\u8853\u3092\u3046\u307e\u304f\u6574\u5408\u3055\u305b\u306a\u304c\u3089\u3001\u591a\u6bb5\u968e\u306e\u5909\u63db\u3092\u9032\u3081\u3066\u3044\u304f\u5fc5\u8981\u304c\u3042\u308a\u307e\u3059\u3002\u3057\u304b\u3057\u3001\u6642\u3068\u3057\u3066\u65e2\u5b58\u306e\u65b9\u6cd5\u8ad6\u306e\u7d44\u307f\u5408\u308f\u305b\u3060\u3051\u3067\u306f\u5168\u304f\u6b6f\u304c\u7acb\u305f\u306a\u3044\u300c\u96e3\u6575\u300d\u3082\u5b58\u5728\u3057\u307e\u3059\u3002\u5f53\u7814\u7a76\u5ba4\u3067\u306f\u3001\u305d\u306e\u3088\u3046\u306a\u5316\u5408\u7269\u306e\u5408\u6210\u3092\u53ef\u80fd\u3068\u3059\u308b\u3001\u3042\u3089\u305f\u306a\u65b9\u6cd5\u8ad6\u306e\u958b\u62d3\u306b\u7a4d\u6975\u7684\u306b\u53d6\u308a\u7d44\u3093\u3067\u304d\u307e\u3059\u3002\uff11\u3064\u306e\u65b0\u3057\u3044\u65b9\u6cd5\u8ad6\u304c\u958b\u767a\u3055\u308c\u308b\u3068\u3001\u3053\u308c\u307e\u3067\u56f0\u96e3\u3067\u3042\u3063\u305f\u5206\u5b50\u5909\u63db\u304c\u975e\u5e38\u306b\u7c21\u5358\u306b\u884c\u3048\u308b\u3088\u3046\u306b\u306a\u308b\u3053\u3068\u304c\u3042\u308a\u307e\u3059\u3002\u3053\u308c\u307e\u3067\u306b\u958b\u767a\u3057\u305f\u81ea\u6162\u306e\u53cd\u5fdc\u3092\u3054\u89a7\u4e0b\u3055\u3044\u3002<\/h3>\n<ul>\n<li><a href=\"#R001\">\u4e0d\u65891,2-\u8ee2\u4f4d\u53cd\u5fdc<\/a>\n<ul>\n<li>\u30d4\u30ca\u30b3\u30fc\u30eb\u578b\u8ee2\u4f4d\u53cd\u5fdc<\/li>\n<li>\u30a8\u30dd\u30ad\u30b7\u30a2\u30eb\u30b3\u30fc\u30eb\u306e\u8ee2\u4f4d\u53cd\u5fdc<\/li>\n<\/ul>\n<\/li>\n<li><a href=\"#R002\">\u30b0\u30ea\u30b3\u30b7\u30eb\u5316\u53cd\u5fdc \uff08\u30e1\u30bf\u30ed\u30bb\u30f3\u6cd5\uff09<\/a><\/li>\n<li><a href=\"#R003\">\u30b7\u30af\u30ed\u30d7\u30ed\u30d1\u30f3\u5316<\/a><\/li>\n<li><a href=\"#R004\">\u30d9\u30f3\u30b6\u30a4\u30f3\u306e\u65b0\u767a\u751f\u6cd5<\/a><\/li>\n<li><a href=\"#R005\">\u30d9\u30f3\u30b6\u30a4\u30f3\u306e\u4ed8\u52a0\u74b0\u5316\u53cd\u5fdc<\/a><\/li>\n<li><a href=\"#R006\">\u30a2\u30ea\u30fc\u30eb C-\u30b0\u30ea\u30b3\u30b7\u30c9\u5316 \uff08<em>O<\/em>\u2192<em>C<\/em>-\u30b0\u30ea\u30b3\u30b7\u30c9\u8ee2\u4f4d\u53cd\u5fdc\uff09<\/a><\/li>\n<li><a href=\"#R007\">\u3072\u305a\u307f\u74b0\u306e\u53cd\u5fdc\uff08\u30d9\u30f3\u30be\u30b7\u30af\u30ed\u30d6\u30c6\u30f3\u306e\u74b0\u62e1\u5927\u53cd\u5fdc\uff09<\/a>\n<ul>\n<li>C=O\u633f\u5165<\/li>\n<li>C=C\u633f\u5165<\/li>\n<li>-O-\u633f\u5165\u3001\u30d5\u30bf\u30ea\u30c9\u30b9\u30eb\u30db\u30f3<\/li>\n<\/ul>\n<\/li>\n<li><a href=\"#R008\">\u3072\u305a\u307f\u74b0\u306e\u53cd\u5fdc\uff08\u30b7\u30af\u30ed\u30d6\u30c6\u30f3\u306e\u5316\u5b66\uff09<\/a>\n<ul>\n<li>S<sub>N<\/sub>2&#8242; (\u4f4d\u7f6e\u9078\u629e\u7684\u306a\u6c42\u6838\u7f6e\u63db\u53cd\u5fdc)<\/li>\n<li>\u7f6e\u63db\u30d3\u30d5\u30a7\u30cb\u30eb\u306e\u5408\u6210 [4+2]<\/li>\n<li>\u7f6e\u63db\u30b7\u30af\u30ed\u30aa\u30af\u30c6\u30f3\u306e\u5408\u6210 [4+2+2]<\/li>\n<\/ul>\n<\/li>\n<li><a href=\"#R009\">\u30d4\u30ca\u30b3\u30fc\u30eb\u74b0\u5316\u53cd\u5fdc\uff08\u30d5\u30a7\u30ca\u30f3\u30c8\u30ec\u30f3\u8a98\u5c0e\u4f53\u306e\u5408\u6210\uff09<\/a><\/li>\n<li><a href=\"#R010\">\u30d2\u30c9\u30ed\u30a2\u30eb\u30df\u30cb\u30a6\u30e0\u5316\u53cd\u5fdc\uff08\u4e09\u7d1a\u30a2\u30eb\u30b3\u30fc\u30eb\u306e\u5408\u6210\uff09<\/a><\/li>\n<li><a href=\"#R011\">\u30d5\u30e9\u30dc\u30ce\u30a4\u30c9\u306e\u5316\u5b66\uff08\u30ab\u30c6\u30ad\u30f3\u30aa\u30ea\u30b4\u30de\u30fc\u306e\u5408\u6210\uff09<\/a><\/li>\n<li><a href=\"#R012\">\u751f\u4f53\u89e6\u5a92\u3092\u7528\u3044\u308b\u5408\u6210\uff08\u975e\u5bfe\u79f0\u5316\u306b\u3088\u308b\u4e0d\u6589\u5408\u6210\uff09<\/a>\n<ul>\n<li>\u30b0\u30ea\u30bb\u30ea\u30c9\u69d8\u5316\u5408\u7269<\/li>\n<li>\u8ef8\u4e0d\u6589\u30d3\u30d5\u30a7\u30cb\u30eb\u306e\u4e0d\u6589\u5408\u6210<\/li>\n<\/ul>\n<\/li>\n<li><a href=\"#R013\">\u30ab\u30eb\u30dc\u30e1\u30bf\u30eb\u5316\u53cd\u5fdc\uff08\u30b8\u30eb\u30b3\u30ce\u30bb\u30f3\u53cd\u5fdc\u5264\u306e\u7279\u6027\uff09<\/a>\n<ul>\n<li>\u30a2\u30eb\u30b1\u30f3\u3068\u30a2\u30ec\u30f3\u306e\u9084\u5143\u7684\u30ab\u30c3\u30d7\u30ea\u30f3\u30b0\u53cd\u5fdc<\/li>\n<li>\u30a2\u30eb\u30ad\u30f3\u985e\u306e\u30a2\u30ea\u30eb\u30e1\u30bf\u30eb\u5316\u53cd\u5fdc<\/li>\n<li>\u30a2\u30eb\u30ad\u30f3\u985e\u306e\u30a2\u30eb\u30ad\u30eb\u30e1\u30bf\u30eb\u5316\u53cd\u5fdc<\/li>\n<\/ul>\n<\/li>\n<li><a href=\"#R014\">\u30cb\u30c8\u30ea\u30eb\u30aa\u30ad\u30b7\u30c9\u3068\u03b2-\u30b8\u30b1\u30c8\u30f3\u306e\u7e2e\u5408\u74b0\u5316\u53cd\u5fdc<\/a><\/li>\n<li><a href=\"#R015\">\u5206\u5b50\u5185\u30d9\u30f3\u30be\u30a4\u30f3\u751f\u6210\u53cd\u5fdc<\/a><\/li>\n<li><a href=\"#R016\">\u30b9\u30d4\u30ed\u30a4\u30bd\u30ad\u30ce\u30ea\u30f3\u9aa8\u683c\u5f62\u6210<\/a><\/li>\n<\/ul>\n<hr \/>\n<h2 id=\"R001\">\u4e0d\u65891,2-\u8ee2\u4f4d\u53cd\u5fdc<\/h2>\n<figure class=\"center\"><img decoding=\"async\" src=\"\/ohmorilab\/wp-content\/themes\/org-synth\/image\/R001.png\" alt=\"\" \/><\/figure>\n<h2 id=\"R002\">\u30b0\u30ea\u30b3\u30b7\u30eb\u5316\u53cd\u5fdc\uff08\u30e1\u30bf\u30ed\u30bb\u30f3\u6cd5\uff09<\/h2>\n<figure class=\"center\"><img decoding=\"async\" src=\"\/ohmorilab\/wp-content\/themes\/org-synth\/image\/R002.png\" alt=\"\" \/><\/figure>\n<h2 id=\"R003\">\u30b7\u30af\u30ed\u30d7\u30ed\u30d1\u30f3\u5316<\/h2>\n<figure class=\"center\"><img decoding=\"async\" src=\"\/ohmorilab\/wp-content\/themes\/org-synth\/image\/R003.png\" alt=\"\" \/><\/figure>\n<h2 id=\"R004\">\u30d9\u30f3\u30b6\u30a4\u30f3\u306e\u65b0\u767a\u751f\u6cd5<\/h2>\n<figure class=\"center\"><img decoding=\"async\" src=\"\/ohmorilab\/wp-content\/themes\/org-synth\/image\/R004.png\" alt=\"\" \/><\/figure>\n<h2 id=\"R005\">\u30d9\u30f3\u30b6\u30a4\u30f3\u306e\u4ed8\u52a0\u74b0\u5316\u53cd\u5fdc<\/h2>\n<figure class=\"center\"><img decoding=\"async\" src=\"\/ohmorilab\/wp-content\/themes\/org-synth\/image\/R005.png\" alt=\"\" \/><\/figure>\n<h2 id=\"R006\">\u30a2\u30ea\u30fc\u30eb <em>C<\/em>-\u30b0\u30ea\u30b3\u30b7\u30c9\u5316\uff08<em>O<\/em>\u2192<em>C<\/em>-\u30b0\u30ea\u30b3\u30b7\u30c9\u8ee2\u4f4d\u53cd\u5fdc\uff09<\/h2>\n<figure class=\"center\"><img decoding=\"async\" src=\"\/ohmorilab\/wp-content\/themes\/org-synth\/image\/R006.png\" alt=\"\" \/><\/figure>\n<h2 id=\"R007\">\u3072\u305a\u307f\u74b0\u306e\u53cd\u5fdc\uff08\u30d9\u30f3\u30be\u30b7\u30af\u30ed\u30d6\u30c6\u30f3\u306e\u74b0\u62e1\u5927\u53cd\u5fdc\uff09<\/h2>\n<figure class=\"center\"><img decoding=\"async\" src=\"\/ohmorilab\/wp-content\/themes\/org-synth\/image\/R007.png\" alt=\"\" \/><\/figure>\n<h2 id=\"R008\">\u3072\u305a\u307f\u74b0\u306e\u53cd\u5fdc\uff08\u30b7\u30af\u30ed\u30d6\u30c6\u30f3\u306e\u5316\u5b66\uff09<\/h2>\n<figure class=\"center\"><img decoding=\"async\" src=\"\/ohmorilab\/wp-content\/themes\/org-synth\/image\/r008.gif\" alt=\"\" \/><\/figure>\n<h2 id=\"R009\">\u30d4\u30ca\u30b3\u30fc\u30eb\u74b0\u5316\u53cd\u5fdc\uff08\u30d5\u30a7\u30ca\u30f3\u30c8\u30ec\u30f3\u8a98\u5c0e\u4f53\u306e\u5408\u6210\uff09<\/h2>\n<figure class=\"center\"><img decoding=\"async\" src=\"\/ohmorilab\/wp-content\/themes\/org-synth\/image\/R009.png\" alt=\"\" \/><\/figure>\n<h2 id=\"R010\">\u30d2\u30c9\u30ed\u30a2\u30eb\u30df\u30cb\u30a6\u30e0\u5316\u53cd\u5fdc\uff08\uff13\u7d1a\u30a2\u30eb\u30b3\u30fc\u30eb\u306e\u5408\u6210\uff09<\/h2>\n<figure class=\"center\"><img decoding=\"async\" src=\"\/ohmorilab\/wp-content\/themes\/org-synth\/image\/R010.png\" alt=\"\" \/><\/figure>\n<h2 id=\"R011\">\u30d5\u30e9\u30dc\u30ce\u30a4\u30c9\u306e\u5316\u5b66\uff08\u30ab\u30c6\u30ad\u30f3\u30aa\u30ea\u30b4\u30de\u30fc\u306e\u5408\u6210\uff09<\/h2>\n<figure class=\"center\"><img decoding=\"async\" src=\"\/ohmorilab\/wp-content\/themes\/org-synth\/image\/r011.gif\" alt=\"\" \/><\/figure>\n<h2 id=\"R012\">\u751f\u4f53\u89e6\u5a92\u3092\u7528\u3044\u308b\u5408\u6210\uff08\u975e\u5bfe\u79f0\u5316\u306b\u3088\u308b\u4e0d\u6589\u5408\u6210\uff09<\/h2>\n<figure class=\"center\"><img decoding=\"async\" src=\"\/ohmorilab\/wp-content\/themes\/org-synth\/image\/R012.png\" alt=\"\" \/><\/figure>\n<h2 id=\"R013\">\u30ab\u30eb\u30dc\u30e1\u30bf\u30eb\u5316\u53cd\u5fdc\uff08\u30b8\u30eb\u30b3\u30ce\u30bb\u30f3\u53cd\u5fdc\u5264\u306e\u7279\u6027\uff09<\/h2>\n<figure class=\"center\"><img decoding=\"async\" src=\"\/ohmorilab\/wp-content\/themes\/org-synth\/image\/r013.gif\" alt=\"\" \/><\/figure>\n<h2 id=\"R014\">\u30cb\u30c8\u30ea\u30eb\u30aa\u30ad\u30b7\u30c9\u3068\u03b2-\u30b8\u30b1\u30c8\u30f3\u306e\u7e2e\u5408\u74b0\u5316\u53cd\u5fdc<\/h2>\n<figure class=\"center\"><img decoding=\"async\" src=\"\/ohmorilab\/wp-content\/themes\/org-synth\/image\/r014.gif\" alt=\"\" \/><\/figure>\n<h2 id=\"R015\">\u5206\u5b50\u5185\u30d9\u30f3\u30be\u30a4\u30f3\u751f\u6210\u53cd\u5fdc<\/h2>\n<figure class=\"center\"><img decoding=\"async\" src=\"\/ohmorilab\/wp-content\/themes\/org-synth\/image\/R015.png\" alt=\"\" \/><\/figure>\n<h2 id=\"R016\">\u30b9\u30d4\u30ed\u30a4\u30bd\u30ad\u30ce\u30ea\u30f3\u9aa8\u683c\u5f62\u6210\uff08\u30aa\u30eb\u30c8\u30ad\u30ce\u30f3\u30a2\u30bb\u30bf\u30fc\u30eb\u306e\u5206\u5b50\u5185\u74b0\u5316\uff09<\/h2>\n<figure class=\"center\"><img decoding=\"async\" src=\"\/ohmorilab\/wp-content\/themes\/org-synth\/image\/R016.png\" alt=\"\" \/><\/figure>\n","protected":false},"excerpt":{"rendered":"<p>\u3000\u8907\u96d1\u306a\u5206\u5b50\u306e\u5408\u6210\u306f\u3001\u3072\u3068\u3064\u306e\u53cd\u5fdc\u3092\u6975\u3081\u305f\u3060\u3051\u3067\u306f\u9054\u6210\u3067\u304d\u307e\u305b\u3093\u3002\u5408\u6210\u6226\u7565\u3068\u6226\u8853\u3092\u3046\u307e\u304f\u6574\u5408\u3055\u305b\u306a\u304c\u3089\u3001\u591a\u6bb5\u968e\u306e\u5909\u63db\u3092\u9032\u3081\u3066\u3044\u304f\u5fc5\u8981\u304c\u3042\u308a\u307e\u3059\u3002\u3057\u304b\u3057\u3001\u6642\u3068\u3057\u3066\u65e2\u5b58\u306e\u65b9\u6cd5\u8ad6\u306e\u7d44\u307f\u5408\u308f\u305b\u3060\u3051\u3067\u306f\u5168\u304f\u6b6f\u304c\u7acb\u305f\u306a\u3044\u300c\u96e3\u6575\u300d\u3082\u5b58 [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"page.php","meta":{"_exactmetrics_skip_tracking":false,"_exactmetrics_sitenote_active":false,"_exactmetrics_sitenote_note":"","_exactmetrics_sitenote_category":0,"footnotes":""},"class_list":["post-41","page","type-page","status-publish","hentry"],"aioseo_notices":[],"_links":{"self":[{"href":"https:\/\/www.org-synth.chem.sci.titech.ac.jp\/index.php?rest_route=\/wp\/v2\/pages\/41","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.org-synth.chem.sci.titech.ac.jp\/index.php?rest_route=\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/www.org-synth.chem.sci.titech.ac.jp\/index.php?rest_route=\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/www.org-synth.chem.sci.titech.ac.jp\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.org-synth.chem.sci.titech.ac.jp\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=41"}],"version-history":[{"count":6,"href":"https:\/\/www.org-synth.chem.sci.titech.ac.jp\/index.php?rest_route=\/wp\/v2\/pages\/41\/revisions"}],"predecessor-version":[{"id":867,"href":"https:\/\/www.org-synth.chem.sci.titech.ac.jp\/index.php?rest_route=\/wp\/v2\/pages\/41\/revisions\/867"}],"wp:attachment":[{"href":"https:\/\/www.org-synth.chem.sci.titech.ac.jp\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=41"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}